基于物流企业数据的2007-2017年中国城市网络空间特征及演化

采用2007、2012和2017年中国百强物流企业网络数据,运用世界城市网络研究的链锁网络模型方法,分析中国城市网络的等级结构、空间分异、空间联系及其演变特征。研究表明：基于物流企业数据的中国城市网络具有明显的层级特征,并呈现“两主多中心”的区域空间结构,网络联系的离散水平逐渐降低,其稳定性和均衡性有所增加,等级结构趋于合理;各节点城市组织能力空间分异明显,京津冀、长三角、珠三角的组织能力和介中心性始终处于较高水平,城市间物流联系逐渐增强,并有协同发展的趋势;城市网络联系中,长江沿线城市物流网络联系地位上升,上海为中心的T字型空间结构替代以北京为中心的核心网络结构,在全国尺度形成以胡焕庸线为界线,物流联系网络呈中东部密集、西部相对稀疏的空间格局,其演变过程呈现由等级网络联系特征向等级性与空间近邻性网络联系特征转变趋势。     

Late Quaternary sea‐level change and evolution of Belfast Lough,Northern Ireland: new offshore evidence and implications for sea‐level reconstruction

The interplay of eustatic and isostatic factors causes complex relative sea‐level (RSL) histories, particularly in paraglacial settings. In this context the past record of RSL is important in understanding ice‐sheet history, earth rheology and resulting glacio‐isostatic adjustment. Field data to develop sea‐level reconstructions are often limited to shallow depths and uncertainty exists as to the veracity of modelled sea‐level curves. We use seismic stratigraphy, 39 vibrocores and 26 radiocarbon dates to investigate the deglacial history of Belfast Lough, Northern Ireland, and reconstruct past RSL. A typical sequence of till, glacimarine and Holocene sediments is preserved. Two sea‐level lowstands (both max. ?40 m) are recorded at c. 13.5 and 11.5k cal a bp . Each is followed by a rapid transgression and subsequent periods of RSL stability. The first transgression coincides temporally with a late stage of Meltwater Pulse 1a and the RSL stability occurred between c. 13.0 and c. 12.2k cal a bp (Younger Dryas). The second still/slowstand occurred between c. 10.3 and c. 11.5k cal a bp . Our data provide constraints on the direction and timing of RSL change during deglaciation. Application of the Depth of Closure concept adds an error term to sea‐level reconstructions based on seismic stratigraphic reconstructions.     

南海东北部内潮的模态结构和传播

The evolution of energy, energy flux and modal structure of the internal tides(ITs) in the northeastern South China Sea is examined using the measurements at two moorings along a cross-slope section from the deep continental slope to the shallow continental shelf. The energy of both diurnal and semidiurnal ITs clearly shows a～14-day spring-neap cycle, but their phases lag that of barotropic tides, indicating that ITs are not generated on the continental slope. Observations of internal tidal energy flux suggest that they may be generated at the Luzon Strait and propagate west-northwest to the continental slope in the northwestern SCS. Because the continental slope is critical-supercritical with respect to diurnal ITs, about 4.6 kJ/m~2 of the incident energy and 8.7 kW/m of energy flux of diurnal ITs are reduced from the continental slope to the continental shelf. In contrast, the semidiurnal internal tides enter the shelf because of the sub-critical topography with respect to semidiurnal ITs.From the continental slope to the shelf, the vertical structure of diurnal ITs shows significant variation, with dominant Mode 1 on the deep slope and dominant higher modes on the shelf. On the contrary, the vertical structure of the semidiurnal ITs is stable, with dominant Mode 1.     

福建大田—漳平地区构造-热对煤系石墨成矿及赋存的控制探讨

福建省大田—漳平地区位于东部滨太平洋构造带上，不同时期的岩浆热液作用和复杂多变的构造形变格局，为该地区形成丰富的石墨矿床提供了良好的成矿条件。为了查明大田—漳平地区煤系石墨的成矿控制因素及分布规律，通过工业分析、元素分析、X射线衍射和激光拉曼光谱等实验，对不同矿区不同变质程度的煤和煤成石墨的化学组成及微观结构特征等煤成石墨化特征进行了研究，并将不同变形特征的样品划分为煤成石墨、煤成半石墨和石墨化无烟煤三大类。研究表明:煤的变形特征与煤成石墨的演化类型基本一致，且韧性变形样品的石墨化程度最高，说明构造应力作用能促进煤的石墨化作用；煤成石墨的分布受到岩浆-构造活动的控制，石墨矿床多产出于岩浆岩侵入体外接触带或附近断裂带的有利围岩地层中，且大田—漳平地区煤系石墨矿具有明显的成区、成带分布特点，煤成石墨成矿区主要集中在闽西南坳陷南部的漳平一带；而北部大田一带分布的矿区矿体石墨化程度较漳平一带低，多为煤成半石墨或石墨化无烟煤，研究结果可为该地区煤系石墨矿产综合勘探开发利用提供有利依据。      

扎鲁特地区无烟煤分子结构特征和模型构建

为了构建内蒙古扎鲁特地区无烟煤的分子结构模型，采用工业分析、元素分析、核磁共振碳谱、高分辨率透射电镜和X射线光电子能谱等测试方法对该地区无烟煤的分子结构进行研究。结果表明无烟煤分子结构中以芳香碳为主，脂肪碳以短烷基侧链和环烷烃为主。煤分子结构中氧原子主要以酚羟基和醚氧基的形式存在，氮原子主要以吡咯型氮和吡啶型氮的形式存在，硫原子主要的赋存形态是硫醇硫酚。结合由核磁共振碳谱测得的煤结构参数和由高分辨率透射电镜测得的芳香环尺寸和含量，构建了无烟煤大分子平均结构模型。对构建的模型进行了结构优化与能量分析，发现煤分子结构的芳香片层趋于平行排列，非键结势能中的范德华力是保持煤结构稳定的主要因素。本研究为采用分子动力学模拟从分子尺度研究扎鲁特地区无烟煤在石墨化过程中，其芳香碳层的拼叠过程及其反应路径提供了模型基础。      

金伯利岩型金刚石矿床研究及其成矿模式探讨——以辽宁瓦房店地区金刚石原生矿矿床为例

辽宁南部瓦房店金刚石矿是国内最大的金刚石矿产区，现已发现4处金刚石成矿带、120个岩体。其中金伯利岩岩管24个、岩脉89个、可疑岩体7个，累计提交1221万克拉储量，占全国金刚石储量52%。本文主要对该矿床的金刚石母岩—金伯利岩的岩石地球化学特征进行了全面系统分析，发现金伯利岩中MgO、NiO、Cr 2O 3的含量与TiO 2、Al 2O 3、Na 2O、K 2O、CaO、P 2O 5等偏碱性组分呈正相关关系；Ni、Cr、Co含量与金刚石含量呈正相关，而Ti、Zr、Ba元素含量与金刚石含量呈负相关。通过对瓦房店矿区金刚石中石榴石及单斜辉石包裹体、橄榄石- 石榴石矿物对、石榴石微量元素、尖晶石- 橄榄石等多种地质温、压计归纳得出金刚石矿的来源深度为150~210 km,压力5~7 GPa，温度1083~1261℃，在上述温、压条件下，结合岩浆化学组成，估算金伯利岩具有低氧逸度(fO 2=2. 913×1. 01325×10-6Pa)的特点。结合野外勘查工作，总结了该矿床的地质特征、控矿构造、矿体空间分布规律等要素，认为NEE向和NE向断裂控制着金伯利岩体的展布方向和矿体形态。脉状金伯利岩体一般呈NEE 70°~80°方向展布，严格受NEE至近EW向的密集节理或裂隙控制。提出了金刚石母岩—金伯利岩是由源于上地幔岩浆，在一定的封闭条件下，受构造与岩性双重控制，多期性的爆发与侵入交替作用所形成，并建立了具有较高氧逸度和较高密度的流变性软流圈，通过渗滤熔体浸蚀岩石圈形成金刚石的理想成因模式，希望为下一步找矿工作提供参考。     

Exploring the database of a soil environmental survey using a geo-self-organizing map: A pilot study

A model integrating geo-information and self-organizing map (SOM) for exploring the database of soil environmental surveys was established. The dataset of 5 heavy metals (As, Cd, Cr, Hg, and Pb) was built by the regular grid sampling in Hechi, Guangxi Zhuang Autonomous Region in southern China. Auxiliary datasets were collected throughout the study area to help interpret the potential causes of pollution. The main findings are as follows: (1) Soil samples of 5 elements exhibited strong variation and high skewness. High pollution risk existed in the case study area, especially Hg and Cd. (2) As and Pb had a similar topo-logical distribution pattern, meaning they behaved similarly in the soil environment. Cr had behaviours in soil different from those of the other 4 elements. (3) From the U-matrix of SOM networks, 3 levels of SEQ were identified, and 11 high risk areas of soil heavy metal-contaminated were found throughout the study area, which were basically near rivers, factories, and ore zones. (4) The variations of contamination index (CI) followed the trend of construction land (1.353) > forestland (1.267) > cropland (1.175) > grassland (1.056), which suggest that decision makers should focus more on the problem of soil pollution surrounding industrial and mining enterprises and farmland.

     

平原地区高潜水位采煤塌陷综合治理研究——以兖州煤田为例

煤炭资源的开采引发了采煤塌陷、农田损毁、生态破坏、农民失地等后果,给矿区带来了一系列经济、社会、环境问题。该文以兖州煤田为例,对平原地区高潜水位条件下煤炭开采引起的地表塌陷现状进行调查,充分掌握了塌陷区土地利用现状、塌陷区稳沉状况及破坏现状。分析了兖州煤田采煤塌陷区的土地损毁特点,研究了塌陷区综合治理的手段和方法,针对性地提出了高潜水位地区采煤塌陷综合治理的途径,为采煤塌陷区的规划治理提供了参考。     

Hydrodynamic performance of a T-shaped floating breakwater

The comprehensive utilization of floating breakwaters, specially acting as a supporting structure for offshore marine renewable energy explorations, has received more and more attention recently. Based on linear water-wave theory, the hydrodynamic performance of a T-shaped floating breakwater is semi-analytically investigated through the matched eigenfunction expansion method (MEEM). Auxiliary functions, to speed up the convergence and improve the accuracy in the numerical computations, are introduced to represent the singular behavior of fluid field near the lower salient corners of the structure. The effects of the height and installation position of the vertical screen on the reflection and transmission coefficients, dynamic response and wave forces are examined. It is found that the presence of the screen shifts the resonance frequency of RAO for both surge and pitch modes to the low-frequency area, while has no effect on heave mode. The identical added masses, damping and transmission coefficients can be obtained in the cases where the screen holds the same distance away from the longitudinal central axis of the upper box-type structure. Moreover, a relatively small pitch response can be achieved in a wide wave–frequency range, when the breakwater is Γ-shaped.     

太行山南端浅层速度结构成像和隐伏断裂探测

利用太行山南端的深地震反射剖面数据，运用初至波层析成像方法反演得到该区域的浅层P波速度结构和基底面展布形态，发现剖面浅部的P波速度变化与沉积盖层厚度和断裂分布有着较好的对应关系。利用跨断裂完成的浅层地震反射剖面，对区域内2条第四纪隐伏活动断裂进行高分辨率成像。结果表明，汤西断裂为东倾的正断层，控制汤阴地堑的西边界，活动年代为中更新世；汤东断裂为西倾的正断层，是汤阴地堑的主控边界断裂，活动年代为晚更新世。